Time value and extrinsic-value describe the same money from different angles. Extrinsic emphasises that it is everything beyond intrinsic; time value emphasises that it decays to zero by expiration-date.
It is not linear. A 90-day option does not hold three times the time value of a 30-day option — it holds roughly the square root of three, about 1.7 times as much, because uncertainty grows with the square root of time.
Example: XYZ at $50 with 20% implied-volatility. The 30-day $50 call costs about $1.15 and the 90-day about $2.00. All of both prices is time value. Sell the 30-day and buy the 90-day and you have paid $0.85 for 60 extra days — the trade behind every calendar-spread.
Related: extrinsic-value, theta, time-decay-curve, calendar-spread